• Introduction

• Global parameters

• Products

• FID conversion

• Canalised emissions

• Storage tank

• Material loading

• Heat variation

• Distillation

• Evaporation

• Purge/Gas sweep
• Empty vessel
• Partially filled

• Depressurisation

• Average factors

• Ranges factors

• Correlation factors

Partially filled vessel purge

Model definition   Launch model

Filled or partially filled vessels are often purged for following reasons:

• Maintain vapour concentration below the inferior explosive limit,
• Inert installation to preserve products quality,
• Etc.

For the evaluation of emissions that occur during partially filled vessel purge operations, applying the standard surface evaporation model is inappropriate (i.e. transfer coefficient are calculated with a wind speed taken at 10 meters above the surface).

Envmodels propose a standard simple model based on a basic evaluation of the degree of VOC saturation for the vent gas. The saturation level depends on following factors:

• Purge flow rate in the vessel,
• Agitation or not in the vessel (quiescent or turbulent liquid surface),
• Specific vessel geometries.

Example:

An agitated reactor is purge with a 10m³/h inert gas. Mass composition of solvents in the reactor is:

• Toluene: 30%,
• MEK: 20%,
• Xylene: 50%.

Temperature of the material in the vessel an the exhaust gas is 25°C (298.15°K). The purge operates 1000 hours per year.

Calculated emissions (for one year) are:

• Toluene: 432.3 kg
• MEK: 980.5 kg
• Xylene: 202.7 kg