Filled or partially filled vessels are often purged for following reasons:
For the evaluation of emissions that occur during partially filled vessel purge operations, applying the standard surface evaporation model is inappropriate (i.e. transfer coefficient are calculated with a wind speed taken at 10 meters above the surface).
Envmodels propose a standard simple model based on a basic evaluation of the degree of VOC saturation for the vent gas. The saturation level depends on following factors:
An agitated reactor is purge with a 10m3/h inert gas. Mass composition of solvents in the reactor is:
Temperature of the material in the vessel an the exhaust gas is 25°C (298.15°K). The purge operates 1000 hours per year.
Calculated emissions (for one year) are: